Show simple item record

dc.contributor.authorMagee, R. J.en
dc.date.accessioned2018-01-31T11:22:46Z
dc.date.available2018-01-31T11:22:46Z
dc.date.issued1965en
dc.identifier.urihttp://hdl.handle.net/1842/26733
dc.description.abstracten
dc.description.abstractThe publications presented in this thesis have been divided into 4 main streams, representing the results of ideas and work in analytical chemistry, carried out in three centres, Department of Chemistry, Queen's University, Belfast; Department of Chemistry, The University, Edinburgh; Department of Chemistry, Case Institute of Technology, Cleveland, Ohio, U.S.Aen
dc.description.abstractThese four main sections are as follows.en
dc.description.abstractA. Analytical Investigations on Transition Metalsen
dc.description.abstractB. Analytical Investigations using Partition Chromatography, Ion-Exchange, and Solvent Extraction.en
dc.description.abstractC. Analytical Investigations on Inorganic Systems using Newer Instrumental Techniquesen
dc.description.abstractD. Analytical Investigations on Inorganic Systems by means of Infrared Spectroscopy.en
dc.description.abstractA. In this section the publications are listed under specific groups of transition metals investigated. These are three in number:en
dc.description.abstract(i) technetium and rhenium, (ii) the Platinum metals, (iii) niobium, tantalum, molybdenum and associated elements.en
dc.description.abstractInvestigations were started on technetium because, at that time, the analytical chemistry of the element was virtually unknown. Technetium (To⁹⁹) extracted from the fission products of U²³⁵, of which the element comprises some 6.2 per cent, was used. The element rhenium was involved as a "guide" for technetium as only small quantities of the latter were available. This proved satisfactory as the analytical chemistry of rhenium itself was by no means well-known. Publications presented in this section deal with the detection of technetium and rhenium, the separation of each from associated and interfering elements and the development of new and more precise methods for their determination.en
dc.description.abstractThe publications presented on the platinum metals indicate work carried out Use other side if necessary. to meet certain deficiencies in the analytical chemistry of these elements. These were, in the main, a lack of small scale methods of determination, and satisfactory methods for rapid separation,en
dc.description.abstractStudies were also carried out on tantalum, molybdenum, and associated elements. The results achieved lure indicated in the publications presented which report rapid colorimetric methods for the determination of niobium, tantalum, molybdenum, titanium and effective means of separation, for analytically and industrially important groups of metals.en
dc.description.abstractB, The publications in this section represent work which was carried out to exploit the use of the separatory techniques of partition chromatography, ion-exchange and solvent extraction particularly for the separation of "difficult" groups of elements.en
dc.description.abstractWhen the investigations started these techniques were quite novel in their application to inorganic systems. Success was achieved with the alkali metals; the alkaline earths; niobium and tantalum; aluminium, gallium, indium, thallium; chromium, tungsten, molybdenum, vanadium; antimony and tin; and others. Consideration was also given to the method of determination of the separated material and, in many oases, new reagents or new techniques were developed,en
dc.description.abstractC, The publications in this section report ideas and subsequent research which was designed to exploit new instrumental methods for the analysis of inorganic substances. The main fields of interest have been grouped under the headings of spectroscopic techniques, which include emission spectroscopy, diffuse reflectance spectroscopy, atomic absorption spectroscopy, and oscillographic polarographyen
dc.description.abstractIn the emission spectroscopy studies attempts were made to utilise "Tesla-luminescence spectra" analytically by developing the earlier principles of Stewart who first observed the phenomenon in 1923. In these studies a new apparatus was designed and developed, and a new technique drawn up and applied to several inorganic systems. The research was extended to flame excitation and later, when atomic absorption spectroscopy became available, investigations were undertaken in this field to exploit the advantages that absorption has over emission methods.en
dc.description.abstractRecently, a new technique - diffuse reflectance spectroscopy became available and offered possibilities for the analysis of the inorganic constituents of precipitates and the study of the structure of substances. Investigations using this technique were carried out resulting in the development of methods for the determination of palladium and cobalt, and the study of the structure of chelates of analytical interest,en
dc.description.abstractPolarographic investigations using "fast sweep" or oscillographic polarography were carried out on the platinum and noble metals. These metals were deliberately chosen because of the inherent difficulties associated with their usual polarography or electrochemistry. The aim of the research was to study the polarography of complexes with different ligands of these metals, in a systematic manner. By this approach it was found possible to obtain complexes giving polarographic half-wave potentials of sufficiently different values to permit the determination of a number of these metals in the presence of one another,en
dc.description.abstractD. In applying infrared methods to inorganic systems, difficulties arise which are inherent to that material and lead to broad absorption peaks and complicated spectra which are of little value analytically. However, by incorporating the ionically bonded inorganic material into a covalently bonded complex, stronger and sharper absorption bands were obtained which, used in conjunction with the alkali halide (KBr) disc technique, were capable of qualitative and quantitative analytical application.en
dc.description.abstractBy this means, methods were developed for the identification and determination of polyatomic inorganic anions, the determination of rhenium and technetium, niobium, tantalum and associated elements, vanadium, molybdenum, tungsten and the study of chelate compounds of analytical interest.en
dc.publisherThe University of Edinburghen
dc.relation.ispartofAnnexe Thesis Digitisation Project 2017 Block 15en
dc.relation.isreferencedbyen
dc.titleStudies in the analytical chemistry of inorganic substancesen
dc.typeThesis or Dissertationen
dc.type.qualificationlevelDoctoralen
dc.type.qualificationnameDSc Doctor of Scienceen


Files in this item

This item appears in the following Collection(s)

Show simple item record