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dc.contributor.authorArnold, Pollyen
dc.contributor.authorMcMaster, J.en
dc.contributor.authorLiddle, S.T.en
dc.date.accessioned2009-08-24T13:14:04Z
dc.date.available2009-08-24T13:14:04Z
dc.date.issued2009-01-01en
dc.identifier.citationArnold P.L., McMaster J., Liddle S.T.. (2009-01-01) An unsupported transition metal-lanthanide bond; synthesis and crystal structure of an Nd-Fe amido N-heterocyclic carbene complex, Chemical Communications 7 818-820en
dc.identifier.issn1359-7345en
dc.identifier.urihttp://www.rsc.org/ej/CC/2009/b819072k.pdfen
dc.identifier.urihttp://dx.doi.org/10.1039/b819072ken
dc.identifier.urihttp://hdl.handle.net/1842/3014
dc.description.abstractA salt-elimination reaction between the neodymium monoiodide [Nd(L)(N)(I)]2 [L = ButNCH2CH2{C(NCSiMe3CHNBut)}; N = N(SiMe3)2] and K[FeCp(CO)2] affords the first complex with an unsupported 4f–3d metal–metal bond that is sufficiently stable to be isolated; the bond is identified as principally ionic in nature by DFT calculations.en
dc.format.extent654244 bytes
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.subjectdonor-acceptor bonds; element thermochemistry; coordination chemistry; disruption enthalpies; molecular-structure; actinide; ligands; reactivity; catalysts; titaniumen
dc.titleAn unsupported transition metal-lanthanide bond; synthesis and crystal structure of an Nd-Fe amido N-heterocyclic carbene complexen
dc.typeArticleen


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