Edinburgh Research Archive

Enantioselective Rhodium-Catalyzed Addition of Potassium Alkenyltrifluoroborates to Cyclic Imines

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dc.contributor.author
Luo, Yunfei
en
dc.contributor.author
Carnell, Andrew J.
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dc.contributor.author
Lam, Hon Wai
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dc.date.accessioned
2013-08-13T11:11:16Z
dc.date.available
2013-08-13T11:11:16Z
dc.date.issued
2012-07-02
dc.description.abstract
Cyclic imines, in which the C[DOUBLE BOND]N bond is constrained in the Z geometry, have been identified as highly effective substrates for enantioselective rhodium-catalyzed additions of potassium alkenyltrifluoroborates. Not only is the alkene in the products a useful functional handle for subsequent manipulations, products containing aryl sulfamates may be employed in nickel-catalyzed Suzuki–Miyaura and Kumada coupling reactions to generate further compounds of interest.
en
dc.identifier.citation
vol 51, number 27, pages 6762-6766
dc.identifier.doi
10.1002/anie.201202136
dc.identifier.issn
1433-7851
dc.identifier.uri
http://hdl.handle.net/1842/7673
dc.language.iso
en
dc.publisher
Angewandte Chemie International Edition
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dc.subject
alkenyltrifluoroborates
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dc.subject
asymmetric catalysis
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dc.subject
enantioselectivity
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dc.subject
imines
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dc.subject
rhodium
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dc.title
Enantioselective Rhodium-Catalyzed Addition of Potassium Alkenyltrifluoroborates to Cyclic Imines
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dc.type
Article
en

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