MacGillivray, William Eoghan.

2018-01-31T11:47:25Z

2018-01-31T11:47:25Z

1928

1. The theory of General Polarity has been applied to the effect of ionisable complexes on the rotatory power of optically active benzoates and holds for ortho,di-methylamino, hydroxy and carboxy esters.

2. The ortho amino ester is a notable exception, which has been explained in view of recent work by Sidgwick on co-ordination compounds, and confirmed by evidence of boiling points and solubilities.

3. The exceptionally high value for the union-ised ortho hydroxy ester has also been explained by Sidgwick's work.

4. The meta and para compounds are unaffected by ionisation except in the case of the hydroxy compounds,the changes in which are governed by the general polar effect.

5. The concentration of the solution has a very marked effect on the rotatory power of the ionised Sodium sec-β-octyl phthalate. A very rapid drop in rotation accompanied by an inversion in sign taking place as the concentration rises. No satisfactory explanation can be advanced to account for this peculiarity.

http://hdl.handle.net/1842/28478

The University of Edinburgh

Annexe Thesis Digitisation Project 2017 Block 16

Already catalogued

Influence of substitution in the benzene ring on optical activity : menthyl esters of di-methylamino, amino, and hydroxy benzoic acids and the octyl phthalates

Thesis or Dissertation

PhD Doctor of Philosophy